2Cr2O7– + 3C2H5OH + 16H+ 4Cr+++ + 3CH3COOH + 11H2O Most of the chemical oxidation methods are based on the complete oxidation of ethanol by dichromate in the presence of sulfuric acid with the formation of acetic acid. Measure the absorbance at 600 nm. Potassium dichromate or anhydrochromate is prepared by adding to the neutral yellow chromate of potassium in solution, a moderate quantity of one of the stronger acids. The method is not environment friendly due to the carcinogenicity of Cr (VI) used. This reaction is highly preferred because potassium dichromate is easily available in high purity and the solution is indefinitely stable in air. Dichromate ion reduces to two chromium (III) ions. The reaction that occurs between alcohol and potassium dichromate is: ¥ç¨‹ç ”究所, data:image/svg+xml;base64,<?xml version='1.0' encoding='iso-8859-1'?>
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<text dominant-baseline="central" text-anchor="start" x='140.765' y='45.6979' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>K</tspan><tspan style='baseline-shift:super;font-size:17.25px;'>+</tspan><tspan></tspan></text>
<text dominant-baseline="central" text-anchor="end" x='61.4799' y='140.344' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan><tspan style='baseline-shift:super;font-size:17.25px;'>-</tspan><tspan></tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='86.1606' y='201.464' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Cr</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='112.97' y='262.939' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="end" x='33.3695' y='236.956' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='147.635' y='165.972' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
<text dominant-baseline="central" text-anchor="middle" x='209.11' y='201.464' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Cr</tspan></text>
<text dominant-baseline="central" text-anchor="start" x='262.138' y='237.311' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan><tspan style='baseline-shift:super;font-size:17.25px;'>-</tspan><tspan></tspan></text>
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<text dominant-baseline="central" text-anchor="start" x='235.919' y='139.989' style='font-size:23px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#E84235' ><tspan>O</tspan></text>
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<text dominant-baseline="central" text-anchor="middle" x='58.7478' y='56.5815' style='font-size:6px;font-style:normal;font-weight:normal;fill-opacity:1;stroke:none;font-family:sans-serif;fill:#3B4143' ><tspan>Cr</tspan></text>
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